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Seminar INFLPR, Miercuri, 8 Noiembrie 2017, ora 11:00, Sectia Laseri, Dr. Ion Sandu: „Autoasamblarea unor nanomateriale prin ablatia laser a unor picaturi depuse pe substrat”

Home Information Research Events Seminars Seminar INFLPR, Miercuri, 8 Noiembrie 2017, ora 11:00, Sectia Laseri, Dr. Ion Sandu: „Autoasamblarea unor nanomateriale prin ablatia laser a unor picaturi depuse pe substrat”

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Seminar INFLPR

Miercuri, 8 Noiembrie 2017, ora 11:00

Sectia Laseri, sala de seminar

Contractul nr.: 4N/2016

Proiectul: PN 16 47 01 01, „Cercetari avansate asupra materiei aflata in conditii extreme”

Faza nr. 17: „Autoasamblarea unor nanomateriale prin ablatia laser a unor picaturi depuse pe substrat”

Termen: 15.10.2017

Responsabil faza: Dr. Ion Sandu

Prezinta: Dr. Ion Sandu

Rezumat: Auto-asamblarea este un fenomen fizic care consta in organizarea autonoma a unor componente in tipare sau structuri ordonate fara interventia omului. Este de doua feluri: a) cvasi-statica, unde procesul are loc la viteze foarte mici (a fost studiat in faza precedenta si continuata partial in faza actuala) si b) dinamica, are loc departe de echilibru si este studiat in faza actuala. Am gasit ca daca un film subtire, lichid al unor saruri ionice in apa este iradiat cu un laser pulsat, se obtine in anumite conditii o serie de cercuri concentrice formate din monocristale ale sarurilor ionice dizolvate, pe care- le-am numit ‘ripples”-uri, in analogie cu ripplesurile formate prin iradierea unei suprafete solide cu laserul in fempto-secunde. Metoda de preparare este urmatoarea: Filme diluate (c = 0.01 − 1%wt.) din solutii de NaCl sau K2CrO4 au fost formate pe lamele de sticla prin intoducere si extragerea verticala a lamelelor din recepiente care contin solutiile. Filmele lichide acopera complet suprafata lamelelor (2.5 × 5.0 cm) si au o grosime d = 2.5 µm. Tinute in pozitie orizontala, filmele lichide obtinute au fost iradiate cu un puls laser la un unghi de incidenta  cu orizontala. Expeimente similare au fost realizate pe solutii coloidale din nanosfere de silica si polistiren de diferite dimensiuni. Analiza imaginilor de microscopie optica au aratat ca: a) interspatierea (perioada) ripplesurilor descreste neliniar catre o valoare constanta, apropiata de lungimea de unda  laserului utilizat b) latimea unui ripples creste cu cresterea unghiului de iradiere  la fel ca in experimentele clasice LIPSS dar nu cu sin or cos ca la acestea. Informatii pe larg pot fi gasite in articolul publicat de noi, „Ion Sandu, Iuliana Urzica, Ana Maria Niculescu, Claudiu Teodor Fleaca, Florian Dumitrache, Maria Badiceanu, Self-organisation of single-crystals as ripple patterns through laser ablation of ionic salt solutions, Applied Surface Science 417 (2017) 160–164.”

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